On the detection of interstellar homonuclear diatomic molecules

Electron Densities for Homonuclear Diatomic Molecules from the Thomas-Fermi-Dirac Theory

Luminescence of Diatomic Molecules

Photoionization has been used to produce ions of N2 , 0 2 . and CO in definite excited states. Deactivating collisions of these ions with molecular gases were described in paper I, where the cross sections of ions with thermal velocity are given for various electronic and vibrational states. By application of an electric field the charged particles are accelerated yielding information on the in...

Spectra of diatomic molecules

Clearly N is perpendicular to R, so the projection of J onto R is the same as the projection LR with eigenvalue ¤1 h of L. (We now reserve z for a direction ̄xed in space, and use the subscript R for a component along R). Because total angular moment of an isolated molecule is constant, eigenfunctions of H when L is non-zero will have the quantum numbers J , MJ , ¤, s (to describe the electronic...

Structure of diatomic molecules

Molecules are of course atoms that are held together by shared valence electrons. That is, most of each atom is pretty much as it would be if the atom were isolated, but one or a few electrons are located in regions (for example, between two atomic cores) where they lead to an overall attractive e®ect. To see roughly how this works, you might consider the case of two protons and two electrons a...

Mass effects in the photodissociation of homonuclear diatomic molecules in helium nanodroplets: inelastic collision and viscous flow energy exchange regimes.

The influence of the mass in the photodissociation dynamics of a homonuclear diatomic molecule (X2), embedded in a superfluid helium nanodroplet (T = 0.37 K) of 300 atoms, has been investigated using a hybrid quantum dynamics method recently proposed by us. Several hypothetical isotopic variants of Cl2 have been examined in order to make possible the analysis of a wide diversity of masses (mX: ...